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Hydrogen exhibits the notable attribute of lacking carbon dioxide emissions when used in internal combustion engines. Nevertheless, hydrogen has a very low energy density per unit volume, along with large emissions of nitrogen oxides and the potential for backfire. Thus, stratified charge combustion (SCC) is used to reduce nitrogen oxides and increase engine efficiency. Although SCC has the capacity to expand the lean limit, the stability of combustion is influenced by the mixture formation time (MFT), which determines the equivalence ratio. Therefore, quantifying the equivalence ratio under different MFT is critical since it determines combustion characteristics. This study investigates the viability of using a Laser Induced Breakdown Spectroscopy (LIBS) for measuring the jet equivalence ratio. Furthermore, study was conducted to analyze the effect of MFT and the double injection parameter, namely the dwell time and split ratio, on the equivalence ratio.

Spark ignition engines utilize catalytic converters to reform harmful exhaust gas emissions such as carbon monoxide, unburned hydrocarbons, and oxides of nitrogen into less harmful products. Aftertreatment devices require the use of expensive catalytic metals such as platinum, palladium, and rhodium. Meanwhile, tightening automotive emissions regulations globally necessitate the development of high-performance exhaust gas catalysts. So, automotive manufactures must balance maximizing catalyst performance while minimizing production costs. There are thousands of different recipes for catalytic converters, with each having a different effect on the various catalytic chemical reactions which impact the resultant tailpipe gas composition. In the development of catalytic converters, simulation models are often used to reduce the need for physical parts and testing, thus saving significant time and money.

The use of hydrogen in internal combustion engines is an effective approach to significantly support the reduction of CO2 emissions from the transportation sector using technically affordable solutions. The use of direct injection is the most promising approach to fully exploit hydrogen potential as a clean fuel, while preserving targets in terms of power density and emissions. In this frame, the development of an effective combustion system largely relies on the hydrogen-air mixture formation process, so to adequately control the charge stratification to mitigate pre-ignitions and knock and to minimize NOx formation. Hence, improving capabilities of designing a correct gas jet-air interaction is of paramount importance. In this paper the analysis of the evolution of a high-pressure gas jet produced by a single-hole prototype injector operated with different pressure ratios is presented.

The environmental and sustainable energy concerns in transport are being addressed through the decarbonisation path and the potential of hydrogen as a zero-carbon alternative fuel. Using hydrogen to replace fossil fuels in various internal combustion engines shows promise in enhancing efficiency and achieving carbon-neutral outcomes. This study presents an experimental investigation of hydrogen (H2) combustion and engine performance in a boosted spark ignition (SI) engine. The H2 engine incorporates both port fuel injection (PFI) and direct injection (DI) hydrogen fuel systems, capable of injecting hydrogen at pressures of up to 4000 kPa in the DI system and 1000 kPa in the PFI operations. This setup enables a direct comparison of the performance and emissions of the PFI and DI operations. The study involves varying the relative air-to-hydrogen ratio (λ) at different speeds to explore combustion and engine limits for categorising and optimising operational regions.

In order to scrutinize the timing variables impacting the combustion performance and emissions of the Port Fuel Injection hydrogen engine (PFI-H2ICE), a model of a four-cylinder hydrogen engine is meticulously built utilizing the 1D software GT-POWER. The effect of excess air coefficients and timing strategies (including the intake valve opening timing (IVO), the start of injection timing (SOI), and ignition timing) is analyzed in this study. The main conclusions are as follows: The hydrogen engine remold from the Isuzu JE4N28 nature gas engine manifests a lean combustion threshold ranging between 2.0 and 2.5. Notably, advancing intake valve opening timing by 20°CA has proven beneficial to the brake thermal efficiency (BTE) of the hydrogen engine while reducing the NOx emissions by a substantial margin, and advancing intake valve opening timing bears the virtue of strengthen the positive influence of the start of injection timing upon the engine's combustion performance.

The Argon Power Cycle (APC) is a novel zero-emission closed-loop argon recirculating engine cycle which has been developed by Noble Thermodynamics Systems, Inc. It provides a significant gain in indicated thermal efficiency of the reciprocating engine by breathing oxygen and argon rather than air. The use of argon, a monatomic gas, greatly increases the specific heat ratio of the working fluid, resulting in a significantly higher ideal Otto cycle efficiency. This technology delivers a substantial improvement in reciprocating engine performance, maximizing the energy conversion of fuel into useful work. Combined Heat and Power (CHP) operating under the APC represents a promising solution to realize a net-zero-carbon future, providing the thermal energy that hard-to-electrify manufacturing processes need while at the same time delivering clean, dispatchable, and efficient power.

The internal combustion engine (ICE) has long dominated the heavy-duty sector by using liquid fossil fuels such as diesel but global commitments by countries and OEMs to reduce lifecycle carbon dioxide (CO2) emissions has garnered interest in alternative fuels like hydrogen. Hydrogen is a unique gaseous fuel that contains zero carbon atoms and has desired thermodynamic properties of high energy density per unit mass and high flame speeds. However, there are challenges related to its adoption to the heavy-duty sector as a drop-in fuel replacement for compression ignition (CI) diesel combustion given its high autoignition resistance. To overcome this fundamental barrier, engine manufacturers are exploring dual fuel combustion engines by substituting a fraction of the diesel fuel with hydrogen which enables fuel flexibility when there is no infrastructure and retrofittability to existing platforms.

Using the recycled waste oils are to be focused for the protection of environment by reducing the land pollution and disposal costs. This study is to use the recycled waste engine oil, waste cooking oil and waste plastic oil along with Bio-butanol from the waste cut vegetables and fruits. Initially, properties and solubility were tested for choosing a suitable blend for fueling into diesel engine from various proportions. These three blends from the base of three waste oils are then tested by modifying and standard engine operating parameters for performance. The properties tests results as 18% of waste engine oil (by volume) with bio-butanol, 16% of waste cooking oil (by volume) with bio- butanol and 24% of waste plastic oil (by volume) with bio-butanol are found competent for fueling engine. These blends produces low efficiency in lower brake powers and the emissions of smoke, hydrocarbons and carbon monoxide are also higher during the operation under standard parameters.

The majority of transportation systems have continued to be powered by the internal combustion engine and fossil fuels. Heavy-duty applications especially are reliant on diesel engines for their high brake efficiency, power density, and robustness. Although engineering developments have advanced engines towards significantly fewer emissions and higher efficiency, the use of fossil-derived diesel as fuel sets a fundamental threshold in the achievable total net carbon reduction. Dimethyl ether can be produced from various renewable feedstocks and has a high chemical reactivity making it suitable for heavy-duty applications, namely compression ignition direct injection engines. Literature shows the successful use of DME fuels in diesel engines without significant hardware modifications.

Biodiesel is a promising alternative to traditional diesel fuel due to its similar combustion properties to diesel and lower carbon emissions on a well-to-wheel basis. However, combusting biodiesel still generates hydrocarbon (HC), CO, NOx and particulate matter (PM) emissions, similar to those from traditional diesel fuel usage. Therefore, aftertreatment systems will be required to reduce these emissions to meet increasingly stringent emission regulations to minimize the impact to the environment. Diesel oxidation catalysts (DOC) are widely used in modern aftertreatment systems to convert unburned HC and CO, to partially convert NO to NO2 to enhance downstream selective catalytic reaction (SCR) catalyst efficiency via fast SCR and to periodically clean-up DPF via controlled soot oxidation. In this work, we focus on the performance difference between biodiesel and diesel over a commercial DOC catalyst to identify the knowledge gap during the transition from diesel fuel to biodiesel.

Biodiesel (i.e., mono-alkyl esters of long chain fatty acids derived from vegetable oils and animal fats) is a renewable diesel fuel providing life-cycle greenhouse gas emission reductions relative to petroleum-derived diesel. With the expectation that there would be widespread use of biodiesel as a substitute for ultra-low sulfur diesel (ULSD), there have been many studies looking into the effects of biodiesel on engine and aftertreatment, particularly its compatibility to the current aftertreatment technologies. The objective of this study was to generate experimental data to measure the effectiveness of a current technology diesel oxidation catalysts (DOC) to oxidize soy-based biodiesel at various blend levels with ULSD. Biodiesel blends from 0 to 100% were evaluated on an engine using a conventional DOC.

Substantial effort has been devoted to utilizing homogeneous charge compression ignition (HCCI) to improve thermal efficiency and reduce emission pollutants in internal combustion engines. However, the uncertainty of ignition timing and limited operational range restrict further adoption for the industry. Using the spark-assisted compression ignition (SACI) technique has the advantage of using a spark event to control the combustion process. This study employs a rapid compression machine to characterize the ignition and combustion process of Dimethyl ether (DME) under engine-like background temperature and pressures and combustion regimes, including HCCI, SACI, and knocking onsite. The spark ignition timing was swept to ignite the mixture under various thermodynamic conditions. This investigation demonstrates the presence of four distinct combustion regimes, including detonation, strong end-gas autoignition, mild end-gas autoignition, and HCCI.

Ethanol blending is one method that can be used to reduce knock in spark ignition engines by decreasing the autoignition reactivity of the fuel and modifying its laminar flame speed. In this paper, the effects of ethanol blending on knock propensity and flame speed of petroleum and low-carbon gasoline fuels is analyzed. To do so, surrogate fuels were formulated for methanol-to-gasoline (MTG) and ethanol-to-gasoline (ETG) based on the fuels’ composition, octane number, and select physical properties; and 0-D and 1-D chemical kinetics simulations were performed to investigate reactivity and laminar flame speed, respectively. Results of MTG and ETG were compared against those of PACE-20, a well-characterized surrogate for regular E10 gasoline. Similarly to PACE-20, blending MTG and ETG with ethanol increases the fuel’s research octane number (RON) and sensitivity.

The use of ammonia (NH3), a low life-cycle carbon fuel, is an increasingly popular pathway towards decarbonization in the marine and other sectors. However, NH3 possesses low reactivity and flame speed, making its use in internal combustion engines challenging. Additionally, combustion of NH3 can produce incomplete combustion, combustion instability, and toxicity concerns related to fuel slip. Therefore, robustly igniting the fuel and promoting effective flame propagation is critical for NH3 usage in engines. In the present study, investigations of NH3 combustion in a 0.4-liter single-cylinder spark-ignited (SI) research engine are carried out experimentally over a range of operating conditions. 100% NH3 operation successfully covers 60% of the speed-load map, while other areas require aid from a secondary fuel. Compared to the gasoline baseline, 7 percentage points higher peak efficiency is realized by NH3, and nitrogen oxides (NOx) emissions are reduced by two thirds.

Ammonia and methanol are both future fuels with carbon-neutral potential. Ammonia has a high octane number, a slow flame speed, and a narrow ignition limit, while methanol has a fast flame speed with complementary combustion characteristics but is more likely to lead to pre-ignition and knock. In this paper, the combustion and emission characteristics of ammonia-methanol solution in a high compression ratio spark ignition engine are investigated. The experimental results show that the peak in-cylinder pressure and peak heat release rate of the engine when using ammonia-methanol solution are lower and the combustion phase is retarded compared with using methanol at the same spark timing conditions. Using ammonia-methanol solution in the engine resulted in a more ideal combustion phase than that of gasoline, leading to an increase in indicated thermal efficiency of more than 0.6% and a wider range of efficient operating conditions.

Low-temperature gasoline combustion (LTGC) engines can provide high efficiencies with very low NOx and soot emissions, but rapid control of the combustion timing remains a challenge. Partial Fuel Stratification (PFS) was demonstrated to be an effective approach to control combustion in LTGC engines. PFS is produced by a double-direct injection (DI) strategy with most of the fuel injected early in the cycle and the remainder of the fuel supplied by a second injection at a variable time during the compression stroke to vary the amount of stratification. Adjusting the stratification changes the combustion phasing, and this can be done on cycle-to-cycle basis by adjusting the injection timing. In this paper, the ability of PFS to control the combustion during wide engine load sweeps is assessed for regular gasoline and gasoline doped with 2-ethylhexyl nitrate (EHN). For PFS, the load control range is limited by combustion instability and poor combustion efficiency at low loads.

Methanol emerges as a compelling renewable fuel for decarbonizing engine applications due to a mature industry with high production capacity, existing distribution infrastructure, low carbon intensity and favorable cost. Methanol’s high flame speed and high autoignition resistance render it particularly well-suited for spark-ignition (SI) engines. Previous research showed a distinct phenomenon, known deflagration-based knock in methanol combustion, whereby knocking combustion was observed albeit without end-gas autoignition. This work studies the implications of deflagration-based knock on noise emissions by investigating the knock intensity and combustion noise at knock-limited operation of methanol in a single-cylinder direct-injection SI engine operated at both stoichiometric and lean (λ = 2.0) conditions. Results are compared against observations from a premium-grade gasoline.

Ammonia (NH3), a zero-carbon fuel, has great potential for internal combustion engine development. However, its high ignition energy, low laminar burning velocity, narrow range of flammability limits, and high latent heat of vaporization are not conducive for engine application. This paper numerically investigates the feasibility of utilizing ammonia in a heavy-duty diesel engine, specifically through low-pressure direct injection (LP-DI) of hydrogen to ignite ammonia combustion. Due to the lack of a well-corresponding mechanism for the operating conditions of ammonia-hydrogen engines, this study serves only as a trend-oriented prediction. The paper compares the engine's combustion and emission performance by optimizing four critical parameters: excess air ratio, hydrogen energy ratio, ignition timing, and hydrogen injection timing. The results reveal that excessively high hydrogen energy ratios lead to an advanced combustion phase, reducing indicated thermal efficiency.

The increased utilization of batteries and fuel-cells for powering electric applications, as well as bio- and e-fuels into internal combustion engines are seen as options to lower the carbon footprint of industry and transportation sectors. When high power outputs and fast refueling are requisites, H2 ICEs may be a relevant choice. Applications include electricity conversion within a genset or mechanical energy in a vehicle. Within this framework, a John Deere 4045 Diesel engine converted to a H2 single-cylinder is studied at relevant operating conditions for the mentioned use cases, which pose high torque and power output requirements. The modified engine integrates a Phinia DI-CHG 10 outward-opening H2 injector instead of the Diesel unit, as well as a spark-plug rather than the glow-plug.

Hydrogen (H2) is commonly considered as one of the most promising carbon-free energy carriers allowing for a decarbonization of combustion applications, for instance by retrofitting of conventional diesel internal combustion engines (ICEs). Although modern H2-ICEs emit only comparably low levels of nitrogen oxides (NOx), efficient catalytic converters are mandatory for exhaust gas after-treatment in order to establish near-zero emission applications. In this context, the present study evaluates the performance of a commercial state-of-the-art oxidation catalyst (OC) and of a catalyst for selective catalytic reduction (SCR) that are typically used for emission reduction from diesel exhausts under conditions representative for H2-fueled ICEs, namely oxygen-rich exhausts with high water vapor levels, comparably low temperatures, and potentially considerable levels of unburnt H2.